- Selective mono-and bis-Au(III) metalations of 5,10,15,20,25,30-Hexaaryl- [26]hexaphyrins(1.1.1.1.1.1)
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Selective mono- and bis-Au(III) metalations of [26]hexaphyrins( 1.1.1.1.1.1) were achieved in a 4:1 mixture of CH2Cl2 and methanol by using Na[AuCl4] as a Au(III) ion source and Ag 3PO4 and Ag2CO3 as Au(III)-activating reagents.
- Naoda, Koji,Mori, Hirotaka,Osuka, Atsuhiro
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supporting information
p. 22 - 24
(2013/03/13)
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- Hexaphyrin fused to two anthracenes
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Gold standard: A bis(AuIII) complex containing the title compound was prepared and characterized (see scheme; DDQ=2,3-dichloro-5,6- dicyano-1,4-benzoquinone, Tf=trifluoromethanesulfonyl). Owing to the effective conjugative network over the flat and elongated rectangular molecular frame, this complex displays a remarkably red-shifted and sharp Q-band-like band at 1467 nm, multiple reversible redox potentials, and a large TPA cross-section value. Copyright
- Naoda, Koji,Mori, Hirotaka,Aratani, Naoki,Lee, Byung Sun,Kim, Dongho,Osuka, Atsuhiro
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supporting information
p. 9856 - 9859
(2012/11/13)
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