Accelerated SuFEx Click Chemistry For Modular Synthesis**
SuFEx click chemistry is a powerful method designed for the selective, rapid, and modular synthesis of functional molecules. Classical SuFEx reactions form stable S?O linkages upon exchange of S?F bonds with aryl silyl-ether substrates, and while near-per
Barrow, Andrew S.,Gialelis, Timothy L.,Homer, Joshua A.,Koelln, Rebecca A.,Moses, John E.,Smedley, Christopher J.
supporting information
(2021/12/10)
SO2F2-Mediated One-Pot Synthesis of Aryl Carboxylic Acids and Esters from Phenols through a Pd-Catalyzed Insertion of Carbon Monoxide
A one-pot Pd-catalyzed carbonylation of phenols into their corresponding aryl carboxylic acids and esters through the insertion of carbon monoxide has been developed. This procedure offers a direct synthesis of aryl carboxylic acids and esters from inexpensive and abundant starting materials (phenols, SO2F2 and CO) under mild conditions. This method tolerates a broad range of functional groups and is also applicable for the modification of complicated natural products.
Fang, Wan-Yin,Leng, Jing,Qin, Hua-Li
supporting information
p. 2323 - 2331
(2017/09/06)
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