141931-12-6Relevant articles and documents
MECHANISM OF PHOSPHINYLOXYSULFONATE FORMATION ON PERACID OXIDATION OF N,N,N',N'-TETRASUBSTITUTED PHOSPHORODIAMIDOTHIOLATES
Wu, Shao-Yong,Toia, Robert F.,Casida, John E.
, p. 4427 - 4430 (2007/10/02)
Peracid oxidation of N,N,N',N'-tetrasubstituted phosphorodiamidothiolates in chloroform yields, among other products, the corresponding phosphinyloxysulfonates via the alkylsulfonic acids by both SN1 and SN2 type mechanisms with their relative contribution determined by the concentration of the sulfonic acid.The first products (t1/2 10-50 min) in the oxidation sequence are tentatively assigned by 1H, 13C and 31P NMR as the phosphorothiolate sulfoxide and sulfone.