142054-92-0Relevant articles and documents
Deconjugation of dehydroamino acids: Stereoselective synthesis of racemic (E)-vinylglycines
Alexander, Paul A.,Marsden, Stephen P.,Munoz Subtil, Dulce M.,Reader, John C.
, p. 5433 - 5436 (2007/10/03)
(Chemical Equation Presented) A practical and general two-step synthesis of carbamate-protected (E)-vinylglycines from aliphatic aldehydes is reported. The key step involves the kinetic α-protonation of dianionic dienolates derived from dehydroamino acids
REACTIONS OF AN ELECTROPHILIC GLYCINE CATION EQUIVALENT WITH GRIGNARD REAGENTS A SIMPLE SYNTHESIS OF β,γ-UNSATURATED AMINO ACIDS
Castelhano, Arlindo L.,Horne, Stephen,Billedeau, Roland,Krantz, Allen
, p. 2435 - 2438 (2007/10/02)
A simple and general synthesis of α-amino acids employing vinyl and alkyl Grignard reagents with a glycine cation equivalent is described.