OXIDATION OF α-DIKETONES BY THE SYSTEM ALUMINUM TRI-tert-BUTYLATE-tert-BUTYL HYDROPEROXIDE
α-Diketones (butanedione, 2,3-pentanedione, benzil) react with tert-butyl hydroperoxide to form the corresponding anhydrides and tert-butyl alcohol.In the reaction of α-diketones with an oxidative system including aluminum tri-tert-butylate and tert-butyl hydroperoxide, tert-butylacylates and peracylates of the corresponding carboxylic acids are formed as the major reaction products.
Stepovik, L. P.,Dodonov, V. A.,Smyslova, G. N.
p. 102 - 106
(2007/10/02)
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