Trifluoromethylthiolation of allylsilanes and silyl enol ethers with trifluoromethanesulfonyl hypervalent iodonium ylide under copper catalysis
Electrophilic trifluoromethylthiolation of allylsilanes and silyl enol ethers with trifluoromethanesulfonyl hypervalent iodonium ylide has been conducted. In the presence of a catalytic amount of CuF2, the reaction proceeded in modest to high y
Arimori, Sadayuki,Takada, Masahiro,Shibata, Norio
supporting information
p. 1063 - 1065
(2015/05/20)
Electrophilic trifluoromethylthiolation of allylsilanes with trifluoromethanesulfanamide
A CH3COCl-promoted allylic trifluoromethylthiolation of allylsilanes with trifluoromethanesulfanamide has been described. The method allows for an efficient synthesis of a wide range of allylic trifluoromethylthiolated compounds under mild conditions.
Liu, Jianbo,Chu, Lingling,Qing, Feng-Ling
supporting information
p. 894 - 897
(2013/03/28)
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