Heteronuclear Cluster Formation: The Synthesis and Structure of the Chloro-bridged Tetranuclear Complex aneS3)>2(PF6)2 Incorporating a Ladder (aneS3 = 1,4,7-Trithiacyclononane)
Treatment of aneS3)>, formed in high yield by reaction of with aneS3, with TlPF6 in CH2Cl2 at 273 K affords the yellow hetero-cluster species aneS3)>2(PF6)2 incorporating a ladder; dissolution of aneS3)>2(PF6)2 in acetone leads to precipitation of TlCl and the formation of the orange chloro-bridged dimer aneS3)>2(PF6)2.
Blake, Alexander J.,Christie, Robert M.,Roberts, Yvonne V.,Sullivan, Martin J.,Schroeder, Martin,Yellowlees, Lesley J.
p. 848 - 850
(2007/10/02)
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