Carbon dioxide as a C1 building block for the formation of carboxylic acids by formal catalytic hydrocarboxylation
A happy marriage of two processes: An effective catalytic system was identified for the direct synthesis of carboxylic acids from non-activated olefins or alcohols, CO2, and H2. Detailed analysis together with labeling studies indicated that the overall hydrocarboxylation of simple olefins results from a combination of the reverse water-gas shift (rWGS) reaction and a hydroxycarbonylation step, each promoted by a rhodium catalyst (see scheme). Copyright
Ostapowicz, Thomas G.,Schmitz, Marc,Krystof, Monika,Klankermayer, Juergen,Leitner, Walter
p. 12119 - 12123
(2013/12/04)
SIDE REACTIONS IN HYDROCARBOXYLATION OF OLEFINS
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Gavrilova, V. M.,Gvozdovskii, G. N.,Rybakov, V. A.,Blanshtein, I. B.,Kuz'mina, G. V.,et al.
p. 1311 - 1313
(2007/10/02)
CARBONYLATION OF OLEFINS AND ALCOHOLS AT ATMOSPHERIC PRESSURE IN THE PRESENCE OF ACID CATALYSTS WITH ADDED Ag2O OR Cu2O
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Pirozhkov, S. D.,Stepanyan, A. S.,Myshenkova, T. N.,Ordyan, M. B.,Lapidus, A. L.
p. 1852 - 1858
(2007/10/02)
CATALYTIC α-ALKYLATION OF ALDEHYDES WITH OLEFINS
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Vinogradov, M. G.,Kovalev, I. P.,Nikishin, G. I.
p. 1265 - 1271
(2007/10/02)
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