- Palladium-catalyzed bond reorganization of 1,3-diynes: An entry to diverse functionalized 1,5-dien-3-ynes
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A mild and efficient method for the synthesis of functionalized 1,5-dien-3-ynes from 1,3-diynes under PdII catalysis is described. The process allows quick and atom-economical assembly of various dihalo-, haloacyl-, and diacyl-substituted 1,5-dien-3-ynes in high yields. The switch of selectivity in the formation of these dienyne products can be controlled by the choice of catalysis system and reaction conditions.
- Wu, Wanqing,Gao, Yang,Jiang, Huanfeng,Huang, Yubing
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p. 4580 - 4586
(2013/06/05)
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