- Acremolin from acremonium strictum is N 2,3-etheno-2′- isopropyl-1-methylguanine, not a 1 H -azirine. Synthesis and structural revision
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The first synthesis of the heterocyclic marine natural product, acremolin, is reported along with the revision of the structure from a 1H-azirine to a substituted N2,3-ethenoguanine (5-methyl-7-isopropyl-4,5- dihydroimidazo[2,1-b]purine). Additional properties of acremolin are also described including its 1H-15N-HMBC and fluorescence spectra.
- Januar, Lawrence A.,Molinski, Tadeusz F.
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p. 2370 - 2373
(2013/07/05)
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