143262-50-4Relevant articles and documents
Benzimidazolo-diazepines from 1,3-dienes and arenediazocyanides through a 1,3,4-tri-aza-Cope rerrangement
Rousselle, Daniel,Ryckmans, Thomas,Viehe, Heinz G.
, p. 5249 - 5258 (2007/10/02)
Cyclic and bicyclic 1-cyano-2-arylhydrazines were prepared from arene diazocyanides and 1,3-dienes. Some of them rearrange at room temperature through a 1,3,4-tri-aza-Cope rearrangement, followed by an intramolecular cyclisation, to afford benzimidazolo-d
Tris-aza-cope rearrangement of bicyclic N-cyano-N'-vinyl or N'-arylhydrazines to imidazolo-diazepine derivatives
Rousselle,Musick,Viehe,Tinant,Declercq
, p. 907 - 910 (2007/10/02)
The bicyclic N-cyanohydrazines 6 and 12 undergo smoothly an unusual isomerisation to the new imidazole-diazepines 9 and 15. The X-ray analysis of structure 9b is reported.