Palladium-acetate catalyst for regioselective direct arylation at C2 of 3-furanyl or 3-thiophenyl acrylates with inhibition of Heck type reaction
Pd(OAc)2/KOAc was found to be an efficient catalytic system for the direct arylation of thiophene and furan derivatives bearing an acrylate at C3. The selectivity of the reaction strongly depends on the nature of the coordinating base. Na2
Chen, Lu,Bruneau, Christian,Dixneuf, Pierre H.,Doucet, Henri
p. 4381 - 4388
(2013/06/27)
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