143697-08-9

Basic information

• Product Name: N-2,1,3-BENZOTHIADIAZOL-4-YL-2,2,2-TRIFLUOROACETAMIDE
• Synonyms: N-2,1,3-BENZOTHIADIAZOL-4-YL-2,2,2-TRIFLUOROACETAMIDE;N-BENZO[1,2,5]THIADIAZOL-4-YL-2,2,2-TRIFLUORO-ACETAMIDE
• CAS NO: 143697-08-9
• Molecular Formula: C8H4F3N3OS
• Molecular Weight: 247.2
• Mol File: 143697-08-9.mol

Chemical Properties

• Appearance: /
• CAS DataBase Reference: N-2,1,3-BENZOTHIADIAZOL-4-YL-2,2,2-TRIFLUOROACETAMIDE(CAS DataBase Reference)
• NIST Chemistry Reference: N-2,1,3-BENZOTHIADIAZOL-4-YL-2,2,2-TRIFLUOROACETAMIDE(143697-08-9)
• EPA Substance Registry System: N-2,1,3-BENZOTHIADIAZOL-4-YL-2,2,2-TRIFLUOROACETAMIDE(143697-08-9)

Safety Data

• Hazardous Substances Data: 143697-08-9(Hazardous Substances Data)

Upstream product

• 767-64-6 4-Amino-2,1,3-benzothiadiazole 
• 407-25-0 trifluoroacetic anhydride 

Relevant articles and documents

Preparation, structure, and amphoteric redox properties of p-phenylenediamine-type dyes fused with a chalcogenadiazole unit

4,7-Bis(dialkylamino)benzo[c][1,2,5]chalcogenadiazoles are a novel class of organic dyes that undergo reversible two-stage one-electron oxidation as well as one-electron reduction. They exhibit absorption maxima in the long-wavelength region, which are assigned as intramolecular charge transfer bands from the phenylenediamine moiety to the electron-accepting heterocycle. Their redox properties as well as molecular and crystal structures are affected by the alkyl substituents on the amino nitrogen and/or by the chalcogen atom (O, S, Se) in the heterocycle.

BENZIDINE TYPE ELECTRON DONORS FUSED WITH 1,2,5-CHALCOGENADIAZOLE UNITS

The title electron donors (1 and 2) were prepared from 4-bromo-7-dialkyl-aminobenzothiadiazole (3).They are electrochemically amphoteric, and the absorption maxima in the 500-550 nm region were assigned to the intramolecular charge-transfer (CT) bands.The X-ray analyses of 1b and 1b radical cation PF6- revealed that the twisted geometry of 1b became planar upon one-electron oxidation, and a coplanar "ribbon"-like network was formed by SN interactions in the crystal of 1b radical cation PF6-.