144284-76-4Relevant articles and documents
A method of preparation of ethylene-propylene-diene rubber
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, (2017/03/23)
The invention discloses a bridged metallocene complex, which is characterized by having a structural formula shown as the following A1, A2, A3 or A4. The invention also discloses a preparation method of ethylene propylene rubber. The ethylene propylene ru
A bridge linking and its application of metal complexes
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Paragraph 0049, (2017/02/23)
The invention discloses a bridged metallocene complex, which is characterized by having a structural formula shown as the following A1, A2, A3 or A4. The invention also discloses a preparation method of ethylene propylene rubber. The ethylene propylene ru
Siloxy substituted metallocene catalysts
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Page/Page column 24, (2008/06/13)
The invention provides a compound of formula (I) or (II) wherein R 1 and R 2 are bound to adjacent carbon atoms and are taken together to form a group -X-SiR' 2 -Y-SiR' 2 -X- or -X-SiR' 2 -X-; each R', which may be the same or different, is a C 1-20 -hydrocarbyl group; each X, which may be the same or different, is O, S, NH; Y is a group X or a bond; each R 3 , which may be the same or different, is a ring substituent or two R 3 groups taken together can form a further optionally R 3 substituted ring (e.g. to form an optionally substituted fluorenyl structure); m is 0 to 5; and n is 0 to 3 and catalysts made using such compounds.
Process for the preparation of amorphous polymers of propylene
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, (2008/06/13)
It is possible to prepare substantially amorphous polymers of propylene endowed with high molecular weights, operating at temperatures of industrial interest, by carrying out the polymerization reaction of propylene in the presence of metallocene catalysts comprising particular bis-indenyl or bis-4,5,6,7-tetrahydroindenyl compounds substituted in the 2-position on the indenyl or tetrahydroindenyl groups.
Crystal structure and propene polymerization characteristics of bridged zirconocene catalysts
Kaminsky, W.,Rabe, O.,Schauwienold, A. -M.,Schupfner, G. U.,Hanss, J.,Kopf, J.
, p. 181 - 194 (2007/10/02)
The synthesis, crystal structure and propene polymerization behaviour of four bridged zirconocene dichlorides is presented.All catalysts are capable of isotactic propene polymerization.Methyl substitutions at the 2-, 4- and 7-positions of the bridged bis(indenyl)zirconocene dichlorides were introduced.The methyl substituent in the 7-position of the indenyl ring induces a significant steric interaction with the bridging group.On comparison of the 2,4,7-methyl substituted catalysts with their unsubstituted counterparts, only the ethylidene bridged catalyst rac-1,2-ethylidene- bis(2,4,7-trimethyl-1-indenyl)zirconium dichloride (4) is forced into the optimum geometry for isotactic propene polymerization.Owing to the steric bulk at the bridge catalyst 4 is very rigid with respect to the movement of the indenyl rings and the metal centre thus produces highly isotatic polypropene even up to high polymerization temperatures.Molecular mechanics calculations and temperature-dependent NMR measurements demonstrate that catalyst 4 is not able to equilibrate between the λ and δ conformational state as the corresponding rac-1,2-ethylidene-bis(-1-indenyl)zirconium dichloride (3) catalyst does.In the case of the catalyst isopropyliden(3-tert-butyl)cyclopentadienyl-9-fluorenyl)zirconium dichloride (6) the substitution in the 3-position changes the symmetry from Cs to C1.This catalyst produces isoactic polypropylene but with a decreased polymerization activity.Keywords: Zirconocene; Homogeneous Ziegler-Natta catalysis; Propene polymerization; Molecular mechanics calculations
Process for preparing cyclopentadienyl group-containing silicon compound or cyclopentadienyl group-containing germanium compound
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, (2008/06/13)
Disclosed is a process for preparing a cyclopentadienyl group-containing silicon compound or a cyclopentadienyl group-containing germanium compound, comprising reacting (i) a lithium, sodium or potassium salt of a cyclopentadiene derivative with (ii) a silicon halide compound or a germanium halide compound in the presence of a cyanide or a thiocyanate. The cyanide or the thiocyanate is preferably a copper salt. According to the process of the invention, a cyclopentadienyl group-containing silicon compound or a cyclopentadienyl group-containing germanium compound, which is very useful for the preparation of a metallocene complex catalyst component, can be prepared in a high yield for a short period of time.
Process for the preparation of substituted indenes
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, (2008/06/13)
The compounds of the formula I or Ia STR1 in which R1 is alkyl, aryl, alkoxy, alkenyl, arylalkyl, alkylaryl, aryloxy, fluoroalkyl, halogenoaryl, alkynyl, trialkylsilyl or a heteroaromatic radical, R2, R3 and R4, in addition to hydrogen, have the meanings given under R1 and R5 is hydrogen, alkyl, fluoroalkyl or alkenyl, can be obtained in a one-stage process by reaction of a compound II STR2 with (substituted) cyclopentadiene in the presence of a base. The compounds I and Ia are suitable as ligands for metallocene complexes which are used as catalysts in olefin polymerization.