Weak arene C-h×××o hydrogen bonding in palladium-catalyzed arylation and vinylation of lactones
Weak force in action: In the title reaction, the palladium catalyst (see figure, left) uses weak CH×××O hydrogen bonding to control the absolute configuration of the new stereocenter. A similar palladium catalyst (right) used conventional NH×××O hydrogen bonding to guide stereoselection. Copyright
Huang, Zhiyan,Chen, Zuliang,Lim, Li Hui,Quang, Gia Chuong Phan,Hirao, Hajime,Zhou, Jianrong
p. 5807 - 5812
(2013/07/05)
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