Reductive amination/cyclization of ω-trifluoromethyl keto esters to trifluoromethylated δ-amino alcohols and lactams
A reductive amination/cyclization approach towards biologically interesting trifluoromethylated four- to seven-membered ring lactams from simply prepared ω-trifluoromethyl keto esters in good to excellent yields has been developed. In addition, trifluorom
Palladium-catalyzed coupling reactions of trifluoroacetimidoyl iodides with olefins and 1-alkynes
Palladium-catalyzed coupling of trifluoroacetimidoyl iodides with olefins and 1-alkynes affords trifluoromethylated α-β-unsaturated imines, which are transformed into nitrogen heterocycles bearing CF3-group.
Uneyama,Watanabe
p. 1459 - 1462
(2007/10/02)
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