146773-64-0

Basic information

• Product Name: allyl 2,4,6-tri-O-benzyl-β-D-glucopyranoside
• Synonyms: allyl 2,4,6-tri-O-benzyl-β-D-glucopyranoside
• CAS NO: 146773-64-0
• Molecular Weight: 490.596
• Mol File: 146773-64-0.mol

Chemical Properties

• CAS DataBase Reference: allyl 2,4,6-tri-O-benzyl-β-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: allyl 2,4,6-tri-O-benzyl-β-D-glucopyranoside(146773-64-0)
• EPA Substance Registry System: allyl 2,4,6-tri-O-benzyl-β-D-glucopyranoside(146773-64-0)

Safety Data

• Hazardous Substances Data: 146773-64-0(Hazardous Substances Data)

Upstream product

• 100-44-7 benzyl chloride 
• 10343-15-4 Acetic acid (2R,3R,4S,5R,6R)-3,5-diacetoxy-2-acetoxymethyl-6-allyloxy-tetrahydro-pyran-4-yl ester 
• 572-09-8 2,3,4,6-tetra-O-acetyl-D-glucopyranosyl bromide 
• 2595-07-5 allyl β-D-glucopyranoside 

Downstream Products

• 122220-84-2 O-(2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)-(1<*>3)-2,4,6-tri-O-benzyl-D-glucopyranose 
• 122220-84-2 O-(2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl)-(1<*>3)-2,4,6-tri-O-benzyl-D-glucopyranose 
• 84396-58-7 allyl O-(2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl)-(1<*>3)-2,4,6-tri-O-benzyl-β-D-glucopyranoside 
• 114055-03-7 allyl O-(2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)-(1<*>3)-2,4,6-tri-O-benzyl-β-D-glucopyranoside 

Relevant articles and documents

A Synthetic Route to Epoxyalkyl β-Laminaribiosides, Especially Suitable for Radiolabelling

The major products in the controlled benzylation (NaH/PhCH2Cl) of allyl and but-3-enyl β-D-glucopyranosides were the 2,4,6-tri-O-benzyl ethers.Subsequent glycosidations of these tribenzyl ethers gave derivatives of allyl and but-3-enyl β-laminaribioside,

Dehydrative Glycosylation Using Heptabenzyl Derivatives of Glucobioses and Lactose

Dehydrative glycosylations of the 2-, 3-, 4-, and 6-OH groups of D-glucopyranose with hepta-O-benzyl derivatives of glucobioses (O-D-glucopyranosyl-(1->n)-D-glucopyranose; n = 2, 3, 4, or 6) and lactose, in the presence of a ternary mixture of p-nitrobenzenesulfonyl chloride, silver trifluoromethanesulfonate, and triethylamine in dichloromethane showed that the selectivity of the reaction depended on the anomeric configuration and the linking position to the reducing tribenzylglucose moiety of the nonreducing tetrabenzylglucosyl residue and on the class of the OH group to be glycosylated.The use of a quaternary mixture of p-nitrobenzenesulfonyl chloride, silver trifluoromethanesulfonate, N,N-dimethylacetamide, and triethylamine made all but the β(1->2)-linked biosyl donor undergo α-condensation.Several new linear trisaccharides were obtained via debenzylation of the condensates.