146954-15-6

Basic information

• Product Name: bis(2-azidobenzyl)amine
• Synonyms: bis(2-azidobenzyl)amine
• CAS NO: 146954-15-6
• Molecular Weight: 279.304
• Mol File: 146954-15-6.mol

Chemical Properties

• CAS DataBase Reference: bis(2-azidobenzyl)amine(CAS DataBase Reference)
• NIST Chemistry Reference: bis(2-azidobenzyl)amine(146954-15-6)
• EPA Substance Registry System: bis(2-azidobenzyl)amine(146954-15-6)

Safety Data

• Hazardous Substances Data: 146954-15-6(Hazardous Substances Data)

Upstream product

• 120692-81-1 1-azido-2-(chloromethyl)benzene 

Downstream Products

• 146954-16-7 tris(2-azidobenzyl)amine 
• 1379600-67-5 bis(2-azidobenzyl)(2-azido-5-chlorobenzyl)amine 
• 1379600-66-4 bis(2-aminobenzyl)(2-amino-5-chlorobenzyl)amine 
• 1379600-63-1 bis{2-[N'-(4-trifluoromethylphenyl)ureido]benzyl}{5-chloro-2-[N'-(4-trifluoromethylphenyl)ureido]benzyl}amine 
• 1379600-62-0 bis{2-[N'-(4-methylphenyl)ureido]benzyl}{5-chloro-2-[N'-(4-methylphenyl)ureido]benzyl}amine 
• 187876-49-9 C₆₂H₅₇N₁₀P₃ 
• 187876-55-7 Tris(2-azidobenzyl)amine N-oxide 

Relevant articles and documents

Tripod-tripod coupling of triazides with triphosphanes. The synthesis, characterization, and stability in solution of new cage compounds: Chiral macrobicyclic triphosphazides

Several examples of a new type of cage compound, chiral macrobicyclic triphosphazides 15, have been prepared by tripod-tripod coupling of tris(2- azidobenzyl)amines with 1,1,1-tris[(diphenylphosphino)methyl] ethane (triphos). The structure determination of C3 or pseudo-C3-symmetric compounds 15 revealed their propellerlike topology, which accounted for their chirality, the rare Z configuration of the three phosphazide units, and a new conformation of the triphos fragment. Compounds 15 decomposed in solution with a phosphane arm-off mechanism, to give rise to complex mixtures instead of the expected tri-λ5-phosphazenes. The stability of 15 in solution was enhanced by the quaternization of the bridgehead nitrogen atom in the form of an N-oxide. Substituents either in the ortho position to the N termini of the phosphazide units or on the benzylic carbon atoms contributed to a decrease in the stability of macrobicycles 15, and in some cases even prevented their preparation.

Synthetic Applications of Bis(iminophosphoranes). One-Pot Preparation of Rigid Bicyclic Guanidines

A one-pot synthesis of , , and bicyclic guanidines based on a new method of dihydropyrimido annelation, which involves reaction of bis(iminophosphoranes) with aryl isocyanates or isothiocyanates is described.The method is also applic