Studies on the chemistry of rapamycin: Novel transformations under Lewis-acid catalysis
The reactivity of rapamycin under mild Lewis-acid catalysis has been investigated. The molecule has been found to be extremely sensitive to basic reagents due to carboxylate elimination β to the C24 ketone. However, transformations normally eff
Luengo,Konialian,Holt
p. 991 - 994
(2007/10/02)
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