Enantioselective Oxazaborolidine Reduction of Ketones Containing Heteroatoms
Ketones which contain heteroatoms, particularly nitrogen, can be enantioselectively and catalytically reduced with chiral oxazaborolidines in the presence of excess borane. Key Words: Enantioselective reduction; Oxazaborolidine; Chiral alcohol; Catalytic reduction; Amine-borane
Optically pure thiazolidinedione alcohols and ethers, and synthetic intermediates for preparing said alcohols and ethers. These compounds have utility as hypoglycemic and hypocholesterolemic agents.
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(2008/06/13)
Process for the preparation of intermediates in the synthesis of chiral thiazolidine-2,4-dione derivatives
A process for the stereoselective preparation of intermediates in the preparation of potent, chiral thiazolidine-2,4-dione hypoglycemics.
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(2008/06/13)
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