LIQUID-PHASE CATALYTIC OXIDATION OF 2-METHOXYMETHYLTHIOPHENE
The oxidation of 2-methoxymethylthiophene with molecular oxygen in the presence of a cobalt bromide catalyst in the kinetic region at 65-100 deg C was investigated.It is shown that the principal products are 2-formylthiophene and methylthiophene-2-carboxylate in a ratio of 1:2.The composition of the products does not depend on the oxidation temperature and changes as the starting concentration of 2-methoxymethylthiophene and the amount of cobalt bromide catalyst are changed.
Leichenko, A. A.,Schedrinskaya, T. V.,Volkov, M. N.
p. 714 - 718
(2007/10/02)
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