- Total synthesis of (R)-(-)-actisonitrile via O-alkylation of optically active 4-hydroxymethyloxazolidin-2-one derivative
-
The enantioselective synthesis of (R)-(-)-actisonitrile 1 has been achieved via O-alkylation of (4R,αS)-4-hydroxymethyl-3-(α-methylbenzyl) oxazolidin-2-one (αS)-4 with 1-iodohexadecane in the presence of CsOH in DMF. Under these reaction conditions, the O
- Sugiyama, Shigeo,Ishida, Akihiro,Tsuchida, Moeko,Ishii, Keitaro
-
p. 1918 - 1923
(2012/02/05)
-
- Synthesis of enantiomerically pure, sn-1 modified sn-2-deoxy-2-amido- glycero-3-phospholipids
-
The synthesis of two types of enantiomerically pure sn-2-deoxy-2-amido- glycero-phospholipids differing in the connection of the alkyl chain at the sn-1-position is described. Both types of lipids were prepared from l-serine- methylester as the chiral starting material. (C) 2000 Published by Elsevier Science Ireland Ltd.
- Bartel, Markus,Rattay, Bernd,Nuhn, Peter
-
p. 121 - 129
(2007/10/03)
-
- A convenient synthesis of 1-ether-2-acylamido-2-deoxy-sn- glycerophospholipids
-
A series of 1-ether-sn-2-acylamidoglycerophospholipids, bearing different polar heads in sn-3-position such as phosphoglycol, -serine, -ethanolamine or -choline, have been prepared. Except for the choline derivative which was synthesized from a β-carbamate alcohol derivative, the remaining compounds were obtained from β-amidoalcohols.
- Garcia,Pascual,Gonzalez,Palomer,Cabre,Andreu,Mauleon,Carganico
-
p. 3165 - 3177
(2007/10/02)
-