15158-90-4

Basic information

• Product Name: (N,N'-propylenebis(2-pyrrolylmethyleneaminato))nickel(II)
• Synonyms: (N,N'-propylenebis(2-pyrrolylmethyleneaminato))nickel(II)
• CAS NO: 15158-90-4
• Molecular Formula: C13H14N4Ni
• Molecular Weight: 284.97046
• Mol File: 15158-90-4.mol

Chemical Properties

• Boiling Point: 414.7°Cat760mmHg
• Flash Point: 204.6°C
• Appearance: /
• Density: g/cm³
• CAS DataBase Reference: (N,N'-propylenebis(2-pyrrolylmethyleneaminato))nickel(II)(CAS DataBase Reference)
• NIST Chemistry Reference: (N,N'-propylenebis(2-pyrrolylmethyleneaminato))nickel(II)(15158-90-4)
• EPA Substance Registry System: (N,N'-propylenebis(2-pyrrolylmethyleneaminato))nickel(II)(15158-90-4)

Safety Data

• Hazardous Substances Data: 15158-90-4(Hazardous Substances Data)

Usage

Uses

Used in Catalysis:
(N,N'-propylenebis(2-pyrrolylmethyleneaminato))nickel(II) is used as a catalyst in the field of organic synthesis for facilitating a wide range of chemical transformations. The nickel ion's ability to participate in various reactions makes this complex a valuable tool in the synthesis of complex organic molecules.
Used in Materials Science:
In the materials science industry, (N,N'-propylenebis(2-pyrrolylmethyleneaminato))nickel(II) is used as a component in the development of new materials. Its unique coordination properties and potential to form more complex structures contribute to the advancement of materials with specific properties and applications.
Used in Coordination Chemistry:
(N,N'-propylenebis(2-pyrrolylmethyleneaminato))nickel(II) serves as a molecular building block in coordination chemistry for constructing more complex coordination compounds. The complex's structural features and coordination capabilities make it a useful starting point for creating novel compounds with tailored properties and functions.

Upstream product

• 373-02-4 nickel diacetate 
• 14942-62-2 N,N'-bis((1H-pyrrol-2-yl)methylene)propane-1,3-diamine 

Relevant articles and documents

Cytotoxicity activity, in silico molecular docking, protein- and DNA-binding study of a new Ni(II) Schiff base complex

One new nickel(II) complex, [Ni(L)] (1), was synthesized from the Schiff base ligand derived from pyrrole-2-carboxaldehyde and 1,3-diaminopropane. Complex 1 was characterized by elemental analysis, IR, UV-Vis and ESI mass spectroscopy, cyclic voltammetry, and single-crystal X-ray structure analysis. Crystallographic results show that two Ni(II) monomeric moieties are present with similar structural features but with slightly different bond lengths and bond angles. The geometry around the Ni(II) center is distorted square planar. DNA-binding properties of complex 1 were well explored by employing UV-Vis and fluorescence spectral methods, cyclic voltammetry, and by viscosity measurements. Similarly the protein-binding study was studied by multispectroscopic techniques using both BSA and HSA. The cytotoxicity study of the compound has also been evaluated. Notably, the in vitro cytotoxicity of complex 1 on two cancer cell lines (AGS and A549) demonstrates that complex 1 has very good anticancer activity. MTT assay, cell-cycle analysis, and annexin-V assay have been performed to know the extent of effect of complex 1 as anticancer agent. Further, in silico molecular docking study revealed that the nickel(II) complex fits into the minor groove of duplex DNA by hydrophobic interaction with functional groups of B-DNA.

Syntheses, characterization and X-ray structure of palladium(II) and nickel(II) complexes of tetradentate pyrrole containing ligands

Palladium(II) and nickel(II) complexes with tetradentate ligands derived from pyrrole 2-carboxaldehyde and various diamines have been synthesized and characterized. The complexes are neutral and the coordination around the metal is square-planar; they are