151827-83-7

Upstream product

• 151830-35-2 methyl N-hydroxy-2-methylphenylcarbamate 
• 151827-82-6 methyl N-(2-methylphenyl)-N-methoxy-carbamate 
• 88-72-2 1-methyl-2-nitrobenzene 
• 611-22-3 N-(o-tolyl)hydroxylamine 
• 151827-85-9 methyl N-ethoxy-N-2-methylphenylcarbamate 

Downstream Products

• 1043911-28-9 C₂₀H₁₈F₆N₂O₄S 
• 1043911-33-6 C₂₀H₁₈F₆N₂O₅ 
• 1257424-08-0 methyl 2-((1-(4-chloro-2-fluoro-5-(methylsulfonamido)phenyl)-3-methyl-5-oxo-1H-1,2,4-triazol-4(5H)-yl)methyl)phenyl(methoxy)carbamate 
• 1257424-09-1 methyl 2-((1-(4-chloro-5-(ethylsulfonamido)-2-fluorophenyl)-3-methyl-5-oxo-1H-1,2,4-triazol-4(5H)-yl)methyl)phenyl(methoxy)carbamate 
• 1257424-10-4 methyl 2-((1-(4-chloro-2-fluoro-5-(phenylsulfonamido)phenyl)-3-methyl-5-oxo-1H-1,2,4-triazol-4(5H)-yl)methyl)phenyl(methoxy)carbamate 
• 1257424-11-5 methyl 2-((1-(2,4-dichloro-5-(methylsulfonamido)phenyl)-3-methyl-5-oxo-1H-1,2,4-triazol-4(5H)-yl)methyl)phenyl(methoxy)carbamate 
• 1257424-12-6 methyl 2-((1-(2,4-dichloro-5-(ethylsulfonamido)phenyl)-3-methyl-5-oxo-1H-1,2,4-triazol-4(5H)-yl)methyl)phenyl(methoxy)carbamate 
• 1257424-13-7 methyl 2-((1-(2,4-dichloro-5-(phenylsulfonamido)phenyl)-3-methyl-5-oxo-1H-1,2,4-triazol-4(5H)-yl)methyl)phenyl(methoxy)carbamate 
• 1607822-60-5 (E)-N-methoxy-N-(2-((1-(1H-benzo[b]thien-2-yl)ethylidene)aminooxy-methyl)phenyl)carbamic acid methyl ester 
• 1607822-61-6 (E)-N-methoxy-N-(2-((4-chloro-1-(1H-benzo[b]thien-2-yl)ethylidene)-aminooxymethyl)phenyl)carbamic acid methyl ester 
• 1607822-62-7 (E)-N-methoxy-N-(2-((5-trifluoromethyl-1-(1H-benzo[b]thien-2-yl)ethylidene)aminooxymethyl)phenyl)carbamic acid methyl ester 
• 1607822-63-8 (E)-N-methoxy-N-(2-((6-ethylthio-1-(1H-benzo[b]thien-2-yl)ethylidene)aminooxymethyl)phenyl)carbamic acid methyl ester 
• 175013-18-0 pyraclostrobin 
• 902760-40-1 methyl N-methoxy-N-[2-[[(3,5,6-trichloropyridin-2-yl)oxo]methyl]phenyl]carbamate 

Relevant academic research and scientific papers

Bactericidal composition containing isotianil and osthole

The invention discloses a bactericidal composition containing isotianil and osthole, and belongs to the technical field of pesticide preparation. The bactericidal composition comprises, by weight, 1-50% of isotianil, 0.1-10% of osthole, 5-10% of a bacteri

Synthesis technology of pyraclostrobin

The invention provides a synthesis technology of pyraclostrobin. The method comprises the following steps that1, ortho-nitrotoluene and NH4Cl are subjected to a reduction reaction under the catalytic action of zinc powder and alloy micro-nano powder; 2, hydroxylamine is subjected to an acylation reaction; 3, a methylation reaction is performed; 4, a bromination reaction is performed to obtain N-methoxy-N-2-methyl bromide methyl phenyl carbamate; 5, DMF is used as a solvent for dissolving the N-methoxy-N-2-methyl bromide methyl phenyl carbamate to prepare a solution for use, 1-(4-chlorphenyl)-pyrazol alcohol, K2CO3 and acetone are placed into a reactor together, heating and reflux are performed, the N-methoxy-N-2-methyl bromide methyl phenyl carbamate solution is added into the reactor slowly, and after the reflux reaction is ended, pyraclostrobin is obtained. Compared with the prior art, the preparation method is simple, raw materials are low in cost and easy to obtain, the reaction conditions are mild, and the obtained target product is high in purity and yield.

Synthesis of site-heterologous haptens for high-affinity anti-pyraclostrobin antibody generation

The design and synthesis of functional chemical derivatives of small organic molecules is usually a key step for the intricate production of a variety of bioconjugates. In this respect, the derivatization site at which the spacer arm is introduced in immunizing conjugates constitutes a highly critical parameter for the generation of high-affinity and selective antibodies. However, due to the usual complexity of the required synthetic procedures, the appropriate comparison of alternative tethering positions has often been neglected. In the present study, meticulous strategies were followed to prepare synthetic derivatives of pyraclostrobin with the same linkers located at diverse rationally-chosen sites. Activity appraisal of antibodies and bioconjugates was carried out by bidimensional competitive direct and indirect immunoassays, and a superior performance of two of the three synthesized haptens was found. Finally, a detailed analysis of the conformations of the target molecule and the synthesized haptens in aqueous solution was done using computer assisted molecular modeling techniques. This study suggested that the lower titers and affinities of one set of antibodies are most probably due to conformational effects of the spacer arm in the immunizing bioconjugate. The Royal Society of Chemistry 2011.

Synthesis and biological activity of novel phenyltriazolinone derivatives

Phenyltriazolinones are one of the most important classes of herbicides targeting the protoporphyrinogen oxidase enzyme. A series of triazolinone derivatives containing a strobilurin pharmacophore were designed and synthesized with the aim of discovering new phenyltriazolinone analogues with high activity. The herbicidal activity of the synthesized compounds was assayed and some of the test compounds displayed moderate herbicidal activity at 150 g ai/ha.

Dihydropyridazinones and pyridazinones and their use as fungicides and insecticides

Compounds with fungicidal and insecticidal properties having formula I wherein W is n is 0 or 1; Y is O, S, NR1, or R6; the ring bond containing R4 and R5 is a single or double bond; X is independently selected from hydrogen, halo, (C1-C4)alkyl, (C1-C4)al

Carbamates and crop protection agents containing them

Carbamates of the formula I STR1 where the substituents have the following meanings: Z is methoxy, NH2, NHCH3, N(CH3)2, CH3, C2 H5, CF3 or CCl3, X and Y are

Dihydropyridazinones and pyridazinones and their use as fungicides and insecticides

Compounds with fungicidal and insecticidal properties having formula I wherein W is n is 0 or 1; Y is O, S, NR1, or R6; the ring bond containing R4and R5is a single or double bond; X is independently selected fr

N-substituted phenylcarbamic acid derivatives, a process for production thereof, agricultural and horticultural fungicides, intermediates of the derivatives and a process for production thereof

An N-substituted phenylcarbamic acid derivative represented by the general formula (I): STR1 [wherein R1 is H, a (C1-6)alkyl group, a halo(C1-6)alkyl group, a (C1-6)alkoxy(C1-6)alkyl group, a (C2

N-Substituted phennylcarbamic acid derivates a process for production thereof, and agricultural and horticultural fungicides

An N-substituted phenylcarbamic acid derivative represented by the general formula: [wherein as disclosed in the specification, each of R1 and R2 is an alkyl group or the like, X is O, S or N(R8), and R3 is -N=C(R4)R5 or the like in the case of X being O], a process for producing said derivative, and an agricultural and horticultural fungicide containing said derivative as an active ingredient.