A Remarkable Base-Induced Rearrangement of Hydroxy Oxazolines to Amido Tetrahydrofurans
Asymmetric β-hydroxy oxazolines heve been shown to rearrange at room temperature to isomeric tetrahydrofurans when deprotonated with potassium hydride in tetrahydrofuran.
Wilson, Kenneth J.,Sabat, Michal,McGarvey, Glenn J.
p. 6180 - 6181
(2007/10/02)
2-PHENYLOXAZOLINES AS CARBOXYLATE PRECURSORS - APPLICATION TO THE SYNTHESIS OF ASYMMETRIC BRANCHED-CHAIN STRUCTURES
A synthetic approach to the title compounds is presented that features the asymmetric elaboration of a chiral, non-racemic oxazoline followed by a two-step oxidative ring cleavage of the heterocycle to a triamide for further transformation.
McGarvey, Glenn J.,Wilson, Kenneth J.,Shanholtz, Carl E.
p. 2641 - 2644
(2007/10/02)
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