- Reaction of Adamantane Alcohols with Bromine
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1-Hydroxyadamantane and 1-hydroxy-3,5,7-trimethyladamantane in the medium of liquid bromine are converted, correspondingly, into 1-bromoadamantane and 1-bromo-3,5,7-trimethyladamantane by substitution of the hydroxy group with molecular bromine. 1-Hydroxyalkyl derivatives of adamantane afford alkyl bromides by means of substitution of the hydroxy groups for bromine with both molecular bromine and, possibly, hydrogen bromide formed upon oxidation of alcohols with bromine. A scheme of substitution of the hydroxy group with molecular bromine is suggested.
- Baklan,Khil'chevskii,Kukhar'
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p. 498 - 505
(2007/10/03)
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