Acyloxylation of 1-methoxycyclohex-1-ene and other enol ethers with dimethyl peroxydicarbonate
Acyloxylation of different types of enol ethers (derived from aldehydes and ketones) by dimethyl peroxydicarbonate (DPDC) results in either addition to the double bond or in a formal replacement of an allylic hydrogen by a methoxycarbonyloxy group forming vicinal oxygenated hydrocarbons. 1,3-Oxygenated products via monoacyloxylation could not be observed. The results are compared with copper(I)-catalyzed acyloxylations of 1-methoxycyclohex-1-ene (1a) by means of tert-butyl peroxycarboxylates 2a, b.
Schank,Beck,Pistorius,Rapold
p. 964 - 968
(2007/10/02)
INITIATION EFFICIENCY OF SOME DIACYL ORGANIC PEROXIDE
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Kochikina, D. G.,Loginova, N. N.,Kulikova, N. M.,Ostrizhko, F. N.,Panshin, Yu. A.
p. 902 - 903
(2007/10/02)
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