Neutron and X-ray diffraction and spectroscopic investigations of intramolecular [C-H...F-C] contacts in post-metallocene polyolefin catalysts: Modeling weak attractive polymer-ligand interactions
A family of Group 4 post-metallocene catalysts, supported by fluorine-functionalized tridentate ligands with the fluorine substituent in the locality of the metal center, is described. For the first time, the contentious C-H...F-C interaction has been cha
Chan, Michael C. W.,Kui, Steven C. F.,Cole, Jacqueline M.,McIntyre, Garry J.,Matsui, Shigekazu,Zhu, Nianyong,Tam, Ka-Ho
p. 2607 - 2619
(2008/02/08)
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