154474-11-0

Basic information

• Product Name: Hexanal, 5-oxo-, 1-(O-methyloxime) (9CI)
• Synonyms: Hexanal, 5-oxo-, 1-(O-methyloxime) (9CI)
• CAS NO: 154474-11-0
• Molecular Formula: C₇H₁₃NO₂
• Molecular Weight: 143.18362
• Product Categories: ACETYLGROUP
• Mol File: 154474-11-0.mol

Chemical Properties

• Boiling Point: 216.7±42.0 °C(Predicted)
• Appearance: /
• Density: 0.94±0.1 g/cm3(Predicted)
• CAS DataBase Reference: Hexanal, 5-oxo-, 1-(O-methyloxime) (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Hexanal, 5-oxo-, 1-(O-methyloxime) (9CI)(154474-11-0)
• EPA Substance Registry System: Hexanal, 5-oxo-, 1-(O-methyloxime) (9CI)(154474-11-0)

Safety Data

• Hazardous Substances Data: 154474-11-0(Hazardous Substances Data)

Upstream product

• 505-03-3 5-oxohexanal 
• 593-56-6 N-methoxylamine hydrochloride 

Relevant articles and documents

N-Methoxy-1,2,4-Dioxazolidines by Ozonolysis Reactions

Ozonolysis of ethyl vinyl ether (7a) in the presence of the O-methylated oxime of cyclohexanone (8) afforded N-methoxy-1,2-dioxa-4-azaspiro[4.5]decane (9a), and ozonolyses of the O-methylated dioximes of 1,4- and 1,5-dicarbonyl compounds (10a-e) afforded N-methoxylated bicyclic 1,2,4-dioxazolidines (12a-e).

Electroorganic Chemistry. 144. Electroreductive Coupling of Ketones with O-Methyl Oximes, N,N-Dimethylhydrazones, amd Nitrones. A Convenient Route to Synthesis of β-Amino Alcohol

The intermolecular coupling of a variety of ketones with some types of O-methyl oximes took place when a mixture of both components was electrochemically reduced in i-PrOH with an Sn cathode.The product, β-methoxyamino alcohol was easily converted to β-amino alcohol by simple reduction.A chiral ligand effective for the enantioselective addition of diethylzinc to an aldehyde was easily obtained from the product formed by the electroreductive coupling of (-)-menthone with O-methylacetaldoxime.The intermolecular coupling of a ketone with a N,N-dimethylhydrazone or nitrone was also promoted by the electroreduction.Furthermore, the electroreductive coupling of a carbonyl group with an intramolecular O-methyl oxime moiety gave the corresponding cyclized product stereoselectively.