155788-86-6Relevant articles and documents
Air-and water-stable catalysts for hydroamination/cyclization. Synthesis and application of CCC-NHC pincer complexes of RH and Ir
Bauer, Eike B.,Andavan, G. T. Senthil,Hollis, T. Keith,Rubio, Ramel J.,Cho, Joon,Kuchenbeiser, Glenn R.,Helgert, Theodore R.,Letko, Christopher S.,Tham, Fook S.
experimental part, p. 1175 - 1178 (2009/04/11)
The scope of CCC-NHC pincer complex synthetic methodology by metalation/transmetalation has been extended to Ir. Structural characterization revealed that it is isomorphous with the Rh complex. Both Rh and Ir complexes are efficient catalysts for the hydr
Electrophile-induced Cyclization of γ,δ-Alkenylimines as a Synthetic Route to Pyrrolidines and Piperidines
Kimpe, Norbert de,Boelens, Mark,Piqueur, Johan,Baele, Jan
, p. 1925 - 1928 (2007/10/02)
Cyclization of γ,δ-alkenylimines with bromine in dichloromethane gave instantaneous formation of cyclic iminium bromides, which were converted into either pyrrolidines of piperidines, depending upon the substitution pattern.This reaction has been applied