- Detection of Ethylenediamine Using a Fluorescent Probe in Solution and in a PMMA Matrix
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Fluorescent 3′,6′-bis(octyloxy)-p-Terphenyl-4,4′-dialdehyde 3 has been successfully synthesized via a Suzuki cross-coupling reaction of the corresponding dibromo compound with a boronic acid compound in the presence of palladium catalyst. The fluorescent
- Kim, Yongkyun,Son, Sang-Ho,Lee, Taek Seung
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- Synthesis of donor-acceptor-type conjugated polymer dots as organic photocatalysts for dye degradation and hydrogen evolution
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Conjugated polymers (CPs) having various donor-acceptor units in the main chain were synthesized via Suzuki coupling reaction for an organic photocatalyst that can generate reactive oxygen species (ROS) for dye degradation and H2 evolution unde
- Gwon, Yougjin,Jo, Seonyoung,Lee, Hyun-Jun,Lee, Taek Seung,Park, Soo Young
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- A Molecular Replication Process Drives Supramolecular Polymerization
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Supramolecular polymers are materials in which the connections between monomers in the polymer main chain are non-covalent bonds. This area has seen rapid expansion in the last two decades and has been exploited in several applications. However, suitable
- Feng, Yuanning,Philp, Douglas
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supporting information
p. 17029 - 17039
(2021/10/25)
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- Bipyridyl ligand and preparation method thereof, ruthenium supramolecular self-assembly body containing bipyridyl ligand and preparation method and application of ruthenium supramolecular self-assembly
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The invention provides a novel bipyridyl bidentate ligand and a preparation method thereof. The structural formula of the novel bipyridyl bidentate ligand is shown in the specification. The inventionfurther provides a ruthenium supramolecular self-assembly body of the ligand and a preparation method of the ruthenium supramolecular self-assembly body. The preparation method comprises the followingsteps: putting a prepared ruthenium receptor and a bipyridyl ligand into a container, adding a mixed solvent of methanol and dichloromethane in equal proportion, stirring for a period of time at roomtemperature, spin-drying the solution to a certain volume after the reaction is finished, slowly adding diethyl ether, and separating out solid powder, namely the ruthenium supramolecular self-assembly body containing the bipyridyl ligand. The self-assembly body is a novel ruthenium-containing self-assembly compound, and has a good inhibition effect on cancer tumor cell lines A549 and HepG-2.
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Paragraph 0030-0036
(2020/08/18)
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- A high efficiency pure organic room temperature phosphorescence polymer PPV derivative for OLED
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For the purpose of improving device efficiency and reducing cost, it is necessary to develop pure organic molecules with room temperature phosphorescence (RTP). A high efficiency pure organic RTP polymer, poly-p-phenylene vinylene (PPV) derivative (Br-PPV-CHO), was designed and synthesized, which possesses a blue emission at 496 nm, an emission lifetime of 14.1 μs, and a photoluminescence quantum yield of 12.2%, and the HOMO and LUMO of ?5.35 eV and ?2.75 eV, respectively, showing a great potential application in the emitting layer of OLED. A device fabricated with the PPV derivative as the emitting material layer shows a max luminance of 194 cd/m2 when the Br-PPV-CHO content was 0.5 wt %, demonstrating the best RTP performance. The good properties of Br-PPV-CHO come from the substituent groups of bromine and aromatic aldehyde, and the molecular structure design strategy in the PPV derivative supplies a useful guidance for the design and syntheses of organic RTP materials.
- He, Ying,Cheng, Nianhe,Xu, Xin,Fu, Jiawei,Wang, Jun-an
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p. 247 - 251
(2018/11/30)
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- Dialkyl-substituted naphtho-dioxodibenzothiophene monomer and preparation method thereof and polymer containing dialkyl-substituted naphtho-dioxodibenzothiophene unit and application of polymer
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The invention discloses a dialkyl-substituted naphtho-dioxodibenzothiophene monomer and a preparation method thereof and a polymer containing a dialkyl-substituted naphtho-dioxodibenzothiophene unit and the application of the polymer. A high-absorption electron unit -SO2- exists in the dialkyl-substituted naphtho-dioxodibenzothiophene monomer, and thus the electron affinity of a molecule can be improved. Through introducing of an unsymmetrical substituting condensed ring structure and an alkyl group, the electron affinity of the monomer can be lowered, and meanwhile, solubleness of the monomer in organic solvent is improved greatly. The dialkyl-substituted naphtho-dioxodibenzothiophene monomer obtains a homopolymer or a copolymer containing the dialkyl-substituted naphtho-dioxodibenzothiophene unit through Suzuki or Stille or Yamamoto polymerization reaction, and the obtained polymer has good solubleness in the organic solvent, is suitable for solution processing, and has wide application prospects in preparation of electroluminescent devices, organic solar cells and organic field effect transistors.
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Paragraph 0073; 0074; 0075; 0076
(2017/08/28)
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- Self-Assembly of Concentric Hexagons and Hierarchical Self-Assembly of Supramolecular Metal-Organic Nanoribbons at the Solid/Liquid Interface
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In an effort to exert more precise control over structural features of supramolecules, a series of giant concentric hexagons were assembled as discrete structures using tetratopic terpyridine (tpy) ligands. In preparation of tetratopic ligand, pyrylium and pyridinium salts chemistry significantly facilitated synthesis. The key compounds were obtained by condensation reactions of pyrylium salts with corresponding primary amine derivatives in good yields. These discrete metallo-supramolecular concentric hexagons were fully characterized by NMR, ESI-MS, TWIM-MS, and TEM, establishing their hexagon-in-hexagon architectures. The combination of different tetratopic ligands also assembled hybrid concentric hexagons with increasing diversity and complexity. Furthermore, these concentric hexagon supramolecules with precisely controlled shapes and sizes were utilized as building blocks to hierarchically self-assemble supramolecular metal-organic nanoribbons (SMON) at solid-liquid interfaces. Ambient STM imaging showed the formation of long 1D SMON rather than 2D assembly on the basal plane of highly oriented pyrolytic graphite (HOPG) surface after simple dropcasting of the solution of preassembled concentric hexagons onto a freshly cleaved surface of HOPG. This wet chemical method based on self-assembly may offer simple, economical, and scalable routes to deliver complex materials.
- Wang, Ming,Wang, Kun,Wang, Chao,Huang, Mingjun,Hao, Xin-Qi,Shen, Ming-Zhan,Shi, Guo-Qing,Zhang, Zhe,Song, Bo,Cisneros, Alejandro,Song, Mao-Ping,Xu, Bingqian,Li, Xiaopeng
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supporting information
p. 9258 - 9268
(2016/08/05)
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- Diverse structures of metal-organic frameworks: Via a side chain adjustment: Interpenetration and gas adsorption
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Three new coordination polymers have been synthesized based on three linear pyridine ligands with different side chains and one flexible V-shaped dicarboxylate co-ligand: {[Co(L1)0.5(sdb)]}n (1), {[Co(L2)0.5(sdb)]·1.5H2O}n (2) and {[Co(L3)0.5(sdb)]·2DMF}n (3) (L1 = E,E-2,5-dioctyloxy-1,4-bis-[2-pyridin-vinyl]-benzene; L2 = E,E-2,5-dibutoxy-1,4-bis-[2-pyridin-vinyl]-benzene; L3 = E,E-2,5-dimethoxy-1,4-bis-[2-pyridin-vinyl]-benzene; H2sdb = 4,4′-sulfonyldibenzoic acid). Complexes 1-3 are 4-connected sql nets with a point symbol of {44·62}. The interpenetration forms and porosity of frameworks have been well controlled by side chain prolongation. A larger steric hindrance for the pendant -OnOct and -OnBut groups leads to a larger repulsive force between the layers and effective construction of inclined polycatenations. A smaller steric hindrance for the pendant -Me group leads to the formation of a parallel stacked network. Therefore, compounds 1 and 2 feature 3D structures with inclined polycatenation (2D + 2D → 3D); compound 3 exhibits a non-interpenetrated 2D + 2D → 2D parallel stacked network. These complexes have been characterized by single crystal X-ray diffraction, infrared spectroscopy, thermogravimetry, elemental analysis, and powder X-ray diffraction measurements. In addition, the gas adsorption properties of the compounds have also been explored.
- Shen, Kang,Qin, Ling,Zheng, He-Gen
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supporting information
p. 16205 - 16210
(2016/10/31)
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- Enhancing Organic Phosphorescence by Manipulating Heavy-Atom Interaction
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Achieving highly efficient phosphorescence in metal-free materials under ambient conditions remains a major challenge in organic optoelectronics. Herein, we report a concise approach to obtaining pure organic phosphorescence with high quantum efficiency of up to 21.9% and millisecond-scale lifetime by manipulating heavy-atom interaction based on a class of dibromobenzene derivatives in the solid state under ambient conditions. By comparing two pairs of the organic compounds designed, the one with two more bromine atoms on the alky terminals (PhBr2C6Br2/PhBr2C8Br2) showed higher luminescence efficiency than the other one (PhBr2C6/PhBr2C8). From the single-crystal analysis, it was proposed that the enhancement of phosphorescence resulted from increased intermolecular heavy-atom interaction in the organic crystals. Furthermore, a temperature sensor was demonstrated by using a model probe of this kind of organic phosphorescent crystals. This work not only provides a concise alternative to enhance phosphorescence in metal-free materials but also extends the scope of pure organic phosphorescent materials with high luminescent efficiency in a single component.
- Shi, Huifang,An, Zhongfu,Li, Pei-Zhou,Yin, Jun,Xing, Guichuan,He, Tingchao,Chen, Hongzhong,Wang, Jingui,Sun, Handong,Huang, Wei,Zhao, Yanli
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p. 808 - 813
(2016/02/18)
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- Supramolecular ruthenium-alkynyl multicomponent architectures: Engineering, photophysical properties, and responsiveness to nitroaromatics
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A series of H-bonded supramolecular architectures were built from monofunctional M-Ci - C-R and bifunctional R-Ci - C-M-Ci - C-R trans-alkynylbis(1,2-bis(diphenylphosphino)ethane)ruthenium(II) complexes and π-conjugated modules containing 2,5-dialkoxy-p-p
- Gatri, Rafik,Ouerfelli, Ines,Efrit, Mohamed Lofti,Serein-Spirau, Francoise,Lere-Porte, Jean-Pierre,Valvin, Pierre,Roisnel, Thierry,Bivaud, Sebastien,Akdas-Kilig, Huriye,Fillaut, Jean-Luc
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supporting information
p. 665 - 676
(2014/03/21)
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- Fluorescent non-linear chiral polymer chemosensor bonded alternatively with 1,4-diethynyl-2,5-dioctyloxybenzene and (R,R)-salen for Zn 2+recognition
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Stereoregular non-linear chiral main chain polymers 1a-b bonded alternatively with (R,R)-salen and 1,4-diethynyl-2,5-dioctyloxybenzene moieties have been synthesized using palladium catalyzed C-C cross-coupling and Schiff base formation reactions as the k
- Sakthivel, Sekarpandi,Jammi, Suribabu,Punniyamurthy, Tharmalingam
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scheme or table
p. 101 - 107
(2012/06/15)
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- Fluorescent OFF-ON polymer chemosensor bonded alternatively with 1,4-dioctyloxybenzene and (R,R)-salen for cascade Zn2+ and chiral recognition
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The synthesis of the chiral main chain polymers 1a-b bonded alternatively with (R,R)-salen and 1,4-dioctyloxybenzene has been described employing a palladium-catalyzed C-C cross-coupling reaction as the key step. They are soluble in common organic solvent
- Sakthivel, Sekarpandi,Punniyamurthy, Tharmalingam
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scheme or table
p. 570 - 576
(2012/08/28)
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- Chiral linear polymers bonded alternatively with salen and 1,4-dialkoxybenzene: Synthesis and application for Ti-catalyzed asymmetric TMSCN addition to aldehydes
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The synthesis of chiral linear polymers 1a-b having salen and 1,4-dioctyloxybenzene as alternate segments has been accomplished. The GPC analysis showed the molecular weights corresponding to ca. 15 (Mw = 10,999, Mn = 9165 and PDI = 1.20) repeating units for 1a and ca. 8 (Mw = 8547, Mn = 7883 and PDI = 1.08) repeating units for 1b. Polymers 1a-b have been studied with Ti(OiPr)4 as a recyclable catalyst for the asymmetric addition of TMSCN to aldehydes while the selectivity of the polymer catalyst is identical to that of the monomer. The reactions are efficient affording the cyanohydrins with up to 88% ee. The selectivity of the polymer based catalyst 9a is found to be the same to that of the monomer 10a. The reaction provides the advantages of simplified product isolation and easy recovery and recyclability of polymer catalyst 9a without any loss of activity or selectivity.
- Sakthivel, Sekarpandi,Punniyamurthy, Tharmalingam
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scheme or table
p. 2834 - 2840
(2011/03/19)
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- Photovoltaic performance of polymers based on dithienylthienopyrazines bearing thermocleavable benzoate esters
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Thermocleavable low-band-gap polymers based on dithienylthienopyrazines were prepared and copolymerized with different donor units like dialkoxybenzene, fluorene, thiophene, and cyclopentadithiophene (CPDT) using both Stille and Suzuki cross-coupling reac
- Helgesen, Martin,Krebs, Frederik C.
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scheme or table
p. 1253 - 1260
(2011/09/21)
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- Effective shielding of triplet energy transfer to conjugated polymer by its dense side chains from phosphor dopant for highly efficient electrophosphorescence
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To examine the quenching of a triplet exciton by low triplet energy (E T) polymer hosts with different chain configurations for high E T phosphor guests, the quenching rate constant measurements were carried out and analyzed by the standard Stern-Volmer equation. We found that an effective shielding of triplet energy transfer from a high ET phosphor guest to a low ET polymer host is possible upon introducing dense side chains to the polymer to block direct contact from the guest such that the possibility of Dexter energy transfer between them is reduced to a minimum. Together with energy level matching to allow charge trapping on the guest, high device efficiency can be achieved. The extent of shielding for the systems of phenylene-based conjugated structures from iridium complexes follows the sequence di-substituted (octoxyl chain) in the para position (dC 8OPPP) is greater than monosubstituted (mC8OPPP) and the PPPs with longer side chains are much higher than a phenylene tetramer (P4) with two short methyl groups. Further, capping the dialkoxyl-susbstituents with a carbazole (Cz) moiety (CzPPP) provides enhanced extent of shielding. Excellent device efficiency of 30 cd/A (8.25%) for a green electrophosphorescent device can be achieved with CzPPP as a host, which is higher than that of dC 8OPPP as host (15 cd/A). The efficiency is higher than those of high ET conjugated polymers, poly(3,6-carbazole) derivatives, as hosts (23 cd/A). This observation suggests a new route for molecular design of electroluminescent polymers as a host for a phosphorescent dopant.
- Huang, Szu-Po,Jen, Tzu-Hao,Chen, Yen-Chun,Hsiao, An-En,Yin, Shu-Hui,Chen, Hsiang-Yun,Chen, Show-An
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p. 4699 - 4707
(2008/09/21)
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- Chiral linear polymers bonded alternatively with salen and 1,4-dialkoxy-2,6-diethynylbenzene: synthesis and application to diethylzinc addition to aldehydes
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The synthesis of chiral polymers 1 bonded alternatively with salen and 1,4-dialkoxy-2,6-diethynylbenzene was accomplished. These polymers are recyclable and catalyze the Et2Zn addition to aldehydes with good enantioselectivity.
- Jammi, Suribabu,Rout, Laxmidhar,Punniyamurthy, Tharmalingam
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p. 2016 - 2020
(2008/02/11)
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- Copolymers of 3,4-ethylenedioxythiophene and of pyridine alternated with fluorene or phenylene units: Synthesis, optical properties, and devices
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We report the synthesis of four conjugated copolymers based on alkylated fluorene or phenylene units which band gap is tuned by the regular insertion of an electron-donating or electron-withdrawing unit, (3,4-ethylenedioxy)thiophene and pyridine, respecti
- Aubert, Pierre-Henri,Knipper, Martin,Groenendaal, Lambertus,Lutsen, Laurence,Manca, Jean,Vanderzande, Dirk
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p. 4087 - 4098
(2007/10/03)
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- Supramolecular ordering, thermal behavior, and photophysical, electrochemical, and electroluminescent properties of alkoxy-substituted yne-containing poly(phenylene-vinylene)s
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The synthesis and the characterization of defect-free alkoxy-substituted yne-containing poly(phenylene-vinylenes) was investigated. It was found that a degree of 7 was obtained for all the polymers enabling a reliable comparison of their properties as a function of the length and geometry of the grafted side chains. A formation of crystalline superstructures of either spherulitic-like or rodlike morphology was identified as following typical nucleation and growth process for polymer having a symmetric substitution pattern. Results show that the high absorption coefficients and high quantum yields in the solid state combined with enhanced oxidation stability made polymers as potential donor materials in the design of organic solar cells.
- Egbe, Daniel Ayuk Mbi,Carbonnier, Benjamin,Ding, Liming,Muehlbacher, David,Birckner, Eckhard,Pakula, Tadeusz,Karasz, Frank E.,Grummt, Ulrich-Walter
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p. 7451 - 7463
(2007/10/03)
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- A general strategy for the synthesis of conjugated polymers based upon the palladium-catalysed cross-coupling of grignard reagents with unsaturated halides
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Palladium-catalysed cross-coupling between aromatic bis-organomagnesium reagents and aromatic dihalides has been experimentally evaluated as a general methodology for the synthesis of soluble conjugated polymers such as poly(p-phenylene)s 6 and 7, poly (p-terphenylenevinylene) 8, poly(phenylenethiophene) 9 and poly (phenylenepyridine) 10. Appropriate experimental conditions were first found in model reactions and then applied to the synthesis of polymers. Molecular mass values were determined both by GPC and by MALDI-TOF spectrometry. The latter technique also permitted accurate determination of the terminal groups of the polymeric chains. Wiley-VCH Verlag GmbH, 69451 Weinheim, Germany, 2002.
- Babudri, Francesco,Colangiuli, Donato,Farinola, Gianluca M.,Naso, Francesco
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p. 2785 - 2791
(2007/10/03)
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- New Rigid Backbone Conjugated Organic Polymers with Large Fluorescence Quantum Yields
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The effect on optical emission of the presence of carbon-carbon triple bond linkages in conjugated aromatic copolymers is studied and leads to fluorescence quantum yields of up to 50percent, substantially higher than most conventional conjugated polymers.
- Davey, Andrew P.,Elliott, Simon,O'Connor, Orla,Blau, Werner
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p. 1433 - 1434
(2007/10/02)
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