Synthesis of Garugamblin-2, a Macrocyclic Diarylheptanoid Constituent of Garuga gamblei
The macrocyclic diarylheptanoid garugamblin-2 (1) and its constitutional and sterical isomers 17-19 were synthesized using the isoxazole derivative 8 for the introduction of the β-methoxyenone function.Ring closure was accomplished by an intramolecular Wittig reaction. - Key Words: Garugamblin-2 / Diarylheptanoids / Macrocycles / Garuga gamblei / Calculations, MMX, PM3
Kaserue, Gyoergy M.,Nogradi, Mihaly,Kajtar-Peredy, Maria
p. 361 - 364
(2007/10/02)
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