Stereoselectivity in the Peterson reaction - Application to the synthesis of BRL 49467
The E:Z selectivity in the introduction of the tri-substituted double bond in BRL 49467 could be controlled by the choice of base and silyl group used in a Peterson olefination reaction. The method allowing optimum E-selectivity was developed such that it
Bell, David,Crowe, Eleanor A.,Dixon, Nicholas J.,Geen, Graham R.,Mann, Inderjit S.,Shipton, Mark R.
p. 6643 - 6652
(2007/10/02)
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