Metal-assisted fragmentation of N-aryl- and -alkyl-N-trimethylsilylaminosulfur chlorides and N-aryl- and -alkyl-aminosulfur chlorides in the presence of conjugated dienes: Synthesis and reactivity of 2-substituted-3,6-dihydro-1,2-thiazines
N-Alkyl- and -aryl-N-trimethylsilylaminosulfur chlorides 2 and N-aryl- and -alkyl-aminosulfur chlorides 8 fragment in the presence of silver ions and a conjugated diene to yield 2-substituted-3,6-dihydro-1,2-thiarines 6 as the major products, possibly via
Bryce, Martin R.,Chesney, Antony,McKelvey, Graham N.,Batsanov, Andrei S.,Howard, Judith A. K.,Anderson, Martin
p. 1825 - 1831
(2007/10/03)
Alkylthionitroso and arylthionitroso compounds generated from N- trimethylsilyl-N-chlorothioalkylamine precursors
A range of alkylthionitroso and arylthionitroso compounds have been generated by thermal fragmentation of N-trimethylsilyl-N- chlorothioalkyl(aryl)amine precursors, and intercepted by reaction with dimethylbutadiene to afford Diels-Alder and ene adducts.
Bryce,Chesney,Heaton,McKelvey,Anderson
p. 5275 - 5278
(2007/10/02)
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