- Extending the stetter reaction with 1,6-acceptors
-
Pace Stetter: A new N-heterocyclic carbene (NHC)-catalysed transformation is described-the intramolecular vinylogous Stetter reaction. This transformation can be effected with both thiazolium and triazolium-based catalysts, using aromatic and aliphatic aldehydes, employing α,β,γ,δ- unsaturated esters, ketones, phosphonates and N-acylpyrroles, and can be conducted enantioselectively (see scheme). Copyright
- Law, Katherine R.,McErlean, Christopher S. P.
-
p. 15852 - 15855
(2014/04/03)
-