A comparative study of conjugated polymers derived from the two 10 π electron circuits of naphthalene and methano [10]annulene is presented. The annulene π topology allows for a greater degree of intrapolymer charge delocalization, a key structural parame
Peart, Patricia A.,Tovar, John D.
p. 3041 - 3044
(2008/02/09)
REGIOSPECIFIC AND SEQUENTIAL SUBSTITUTION OF TRIMETHYLSILYL-1,6-METHANOANNULENES VIA THE ELECTROPHILIC ipso-REACTION
2-Substituted 7-trimethylsilyl-1,6-methanoannulenes have been prepared and their electrophilic ipso-desilyl-substitution has been studied, providing a new route for the regiospecific polyfunctionalization of 1,6-methanoannulenes.
Takahashi, Kazuko,Ohnishi, Keiichi,Takase, Kahei
p. 1079 - 1082
(2007/10/02)
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