15825-93-1

Basic information

• Product Name: 2,7-Dibromo-1,6-methano[10]annulene
• Synonyms: 2,7-Dibromo-1,6-methano[10]annulene
• CAS NO: 15825-93-1
• Molecular Formula: C₁₁H₈Br₂
• Molecular Weight: 299.99
• Mol File: 15825-93-1.mol

Chemical Properties

• Boiling Point: 426.9°Cat760mmHg
• Flash Point: 248°C
• Appearance: /
• Density: 1.8g/cm³
• Vapor Pressure: 4.24E-07mmHg at 25°C
• Refractive Index: 1.684
• CAS DataBase Reference: 2,7-Dibromo-1,6-methano[10]annulene(CAS DataBase Reference)
• NIST Chemistry Reference: 2,7-Dibromo-1,6-methano[10]annulene(15825-93-1)
• EPA Substance Registry System: 2,7-Dibromo-1,6-methano[10]annulene(15825-93-1)

Safety Data

• Hazardous Substances Data: 15825-93-1(Hazardous Substances Data)

Usage

Class of Compound

Polycyclic/hypercondensed arenes

Physical Properties

Colorless solid, insoluble in water, soluble in organic solvents

Uses

Organic synthesis, research, building block for more complex chemicals, potential applications in materials science and pharmaceuticals

Availability

Limited commercial availability, not widely used in industrial applications

InChI:InChI=1/C11H8Br2/c12-10-5-1-3-8-7-9(10)4-2-6-11(8)13/h1-6H,7H2

Upstream product

• 15825-92-0 2-bromo-1,6-methano[10]annulene 
• 102836-12-4 (7-Bromo-bicyclo[4.4.1]undeca-1,3,5,7,9-pentaen-2-yl)-trimethyl-silane 
• 2443-46-1 1,6-methano[10]annulene 
• 102836-11-3 2,7-bis(trimethylsilyl)-1,6-methano<10>annulene 

Downstream Products

• 40563-42-6 1,6-Methano-<10>annulen-2-carbaldehyd 
• 72939-26-5 rac-1,6-Methano-<10>annulen-2,7-dicarbaldehyd 
• 2443-46-1 1,6-methano[10]annulene 
• 196412-25-6 7-Bromo-2-(4-nitro-phenylethynyl)-bicyclo[4.4.1]undeca-1⁽¹⁰⁾,2,4,6,8-pentaene 
• 94632-73-2 2,7-Dimethoxy-1,6-methano<10>annulene 
• 295775-77-8 2-Bromo-7-methoxy-1,6-methano[10]annulene 

Relevant articles and documents

Methano[10]annulene revisited: Extended delocalization through conjugated polymers bearing larger Hueckel aromatics

A comparative study of conjugated polymers derived from the two 10 π electron circuits of naphthalene and methano [10]annulene is presented. The annulene π topology allows for a greater degree of intrapolymer charge delocalization, a key structural parame

REGIOSPECIFIC AND SEQUENTIAL SUBSTITUTION OF TRIMETHYLSILYL-1,6-METHANOANNULENES VIA THE ELECTROPHILIC ipso-REACTION

2-Substituted 7-trimethylsilyl-1,6-methanoannulenes have been prepared and their electrophilic ipso-desilyl-substitution has been studied, providing a new route for the regiospecific polyfunctionalization of 1,6-methanoannulenes.