Nucleophilic reactions between cyclic 1,2-sulfites and chloride ions
When cyclic 1,2-sulfites are ring opened by chloride ion, the chlorohydrins are formed with low regio- and stereo-selectivity. The mechanisms involved in the process were investigated by measuring the stereochemical outcome of the reactions. The results showed that reversible inversion pathways (SN2 reactions) and a retention pathway (SN2i reaction) gave rise to the loss in ee in both the chlorohydrins and in the cyclic 1,2-sulfites. Acta Chemica Scandinavica 1996.
Nymann, Kirsten,Jensen, Linda,Svendsen, John S.
p. 832 - 841
(2007/10/03)
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