Stereoselective Synthesis of Exocyclic Allylsilanes by Intramolecular Reductive Heck Cyclisation of Propargylsilanes
The stereoselective palladium-catalysed synthesis of the heterocycles 13-15 with a (Z)-exocyclic allylsilane moiety is described.Alkylation of the secondary amides 5a, 5b, 9a, and 9b and the phenol 11 containing an iodoaryl moiety with the propargyl iodid
Tietze, Lutz F.,Schimpf, Ralph
p. 2235 - 2240
(2007/10/02)
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