C(sp3)-C(sp3) bond formation via copper/ Bronsted acid co-catalyzed C(sp3)-H bond oxidative cross-dehydrogenative-coupling (CDC) of azaarenes
A copper/Bronsted acid dual-catalyst promoted oxidative cross-dehydrogenative-coupling of alkylazaarenes and tertiary amines for C(sp3)-C(sp3) bond formation was developed. This method uses dioxygen as the terminal oxidant under mild reaction conditions and would provide a convenient benzylic C-H transformation of alkylazaarenes to biologically active pharmaceutics. the Partner Organisations 2014.
Wang, Fang-Fang,Luo, Cui-Ping,Deng, Guojun,Yang, Luo
supporting information
p. 2428 - 2431
(2014/05/06)
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