A Rh-catalyzed regio- and stereoselective route to enamides: Benzamides as assembling reagents
A new protocol for the synthesis of fully substituted enaminones has been achieved using a diverse range of benzamides and 1-sulfonyl-1,2,3-triazoles. Selective removal of the β-amino moiety of the obtained α-amido-enaminones to form Z-enamides was also demonstrated thus improving the synthetic value of benzamides for structural diversities in a minimum number of synthetic steps. This journal is the Partner Organisations 2014.
Lee, Dong Jin,Shin, Jinhwan,Yoo, Eun Jeong
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p. 6620 - 6622
(2014/06/10)
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