Straightforward access to chalcogenoureas derived from N-heterocyclic carbenes and their coordination chemistry
Chalcogen-based urea compounds supported by a wide range of N-heterocyclic carbenes are synthesised and fully characterised. Coordination of selenoureas is further explored with Group 11 transition metals to form new copper, gold and silver complexes. Sin
A. C. A. Bayrakdar, Tahani,Nahra, Fady,Nelson, David J.,Nolan, Steven P.,Saab, Marina,Tzouras, Nikolaos V.,Van Hecke, Kristof
p. 12068 - 12081
(2020/09/21)
Determining the Ligand Properties of N-Heterocyclic Carbenes from 77Se NMR Parameters
The 1JCSe coupling constants for a range of NHC-selenium adducts have been measured and used to establish a correlation with the σ-donor strength of the respective carbenes. For the subclass of amido-carbenes, the 1JC
Verlinden, Kathrin,Buhl, Hannes,Frank, Walter,Ganter, Christian
p. 2416 - 2425
(2015/05/20)
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