Synthesis of (endo) 3,9-Disubstituted Diazabicyclononan-7-amines
The novel synthesis of a series of 3,9-diazabicyclononan-7-amines (4) is reported via an alane reduction of a key intermediate oxime (8).The stereoselectivity of the reduction is highly dependent on the size of the 3-aza substituent.
Gregory, J. A.,Jennings, A. J.,Joiner, G. F.,King, F. D.,Rahman, S. K.
p. 155 - 158
(2007/10/02)
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