Effect of substituents on the silicon atom on etherification of organochlorosilanes with ethanol
The kinetics of etherification of organochlorosilanes with various substituents on the silicon atom with ethanol were studied. The etherification rate is mostly controlled by the inductive constants of the substituents and increases as the electron-acceptor power of the substituents increases. The ρ* value in the Taft equation for etherification of organochlorosilanes with ethanol was determined.
Chernyshev,Belyakova,Komarov,Bykovchenko
p. 1038 - 1040
(2007/10/03)
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