Copper-catalyzed cycloaddition between hydrogen phosphonates and activated alkenes: Synthesis of phosphonoisoquinolinediones
A new, general method for the synthesis of phosphonoisoquinolinediones has been achieved via copper-catalyzed phosphonation-cyclization of various methacryloylbenzamides with P(O)H compounds. This transformation allows the direct formation of a P-C bond a
Arylphosphonylation and arylazidation of activated alkenes
Two radical-mediated processes of activated alkenes, namely arylphosphonylation and arylazidation, are described. The difunctionalization of alkenes by a tandem process that involves radical addition, 1,4-aryl migration, and desulfonylation generates α-ar
Kong, Wangqing,Merino, Estibaliz,Nevado, Cristina
supporting information
p. 5078 - 5082
(2014/05/20)
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