- SYNTHETIC METHODS PERTAINING TO TERT-BUTYL-BENZENE-BASED COMPOUNDS
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According to some aspects, the present disclosure pertains to methods of forming dimethyl 5-tert-butylisophthalate which comprise comprising converting 5-tert-butylisophthalic acid into dimethyl 5-tert-butylisophthalate in synthesis procedures that compri
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Paragraph 0035; 0036; 0037; 0038
(2013/07/31)
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- C3-Symmetric chiral trisimidazoline: The role of a third imidazoline and its application to the nitro Michael reaction and the α-amination of β-ketoesters
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We describe the necessity of the C3-symmetry and the role of a third imidazoline of trisimidazoline 3, which was recently developed by us as a new entry of organocatalyst. The utility of 3 as a Br?nsted base catalyst in the nitro Michael reaction and the α-amination of β-ketoesters was shown, and the recyclability of the catalyst was also demonstrated.
- Murai, Kenichi,Fukushima, Shunsuke,Nakamura, Akira,Shimura, Masato,Fujioka, Hiromichi
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experimental part
p. 4862 - 4868
(2011/08/03)
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- BISAMIDE CYTOKINE INHIBITORS
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The present invention provides low molecular weight compounds useful as cytokine inhibitors, and compositions thereof. In particular, compounds of the invention are bisamides and are useful as anti-inflammatory agents. In one aspect the compounds have the
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Page/Page column 110
(2008/06/13)
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- HETEROCYCLIC CYTOKINE INHIBITORS
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The present invention provides low molecular weight compounds useful as cytokine inhibitors, and compositions thereof. In particular, compounds of the invention are useful as anti-inflammatory, anti-pain or anti-cancer agents. There are further provided m
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Page/Page column 136
(2010/11/27)
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- Chemo- and regioselective cyclotrimerization of monoynes catalyzed by a nickel(0) and zinc(II) phenoxide system
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A binary metal system of nickel(0) and zinc(II) phenoxide catalyzed the chemo- and regioselective cyclotrimerization of monoynes.
- Mori,Ikeda,Odashima
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p. 181 - 182
(2007/10/03)
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- Dimetalation: The acidity of monometalated arenes towards superbasic reagents
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Twofold hydrogen/metal interconversions ("dimetalations") can be accomplished with "spiny" arenes (tert-butylbenzene, 1,4-di-tert-butylbenzene, 1,1,3,3-tetramethylindane and congeners) and N,N-crowded anilines (2,2,6,6-tetramethyl-1-phenylpiperidine and N
- Baston, Eckhard,Maggi, Raimondo,Friedrich, Kirstin,Schlosser, Manfred
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p. 3985 - 3989
(2007/10/03)
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- Synthesis of 2,5- and 2,4-cyclohexadiene-1,3-dicarboxylates via reductive alkylation of isophthalates
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Substituted 2,5-(structure 1) and 2,4-(structure 2) cyclohexadiene-1,3-dicarboxylates were prepared via Birch reductive alkylation of substituted isophthalates with alkylating agents such as alkyl and allyl halides, alkyl dihalides, α-halocarboxylates and expoxides. A brief discussion about their reactivity and stability is presented.
- Seneci, Pierfausto,Caspani, Marco,Monti, Federica,Carrano, Lucia,Lociuro, Sergio,Ciabatti, Romeo
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p. 795 - 809
(2007/10/03)
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