1632070-90-6

Basic information

• Product Name: C₇H₅BF₅^(1-)*K⁽¹⁺⁾
• Synonyms: C₇H₅BF₅^(1-)*K⁽¹⁺⁾
• CAS NO: 1632070-90-6
• Molecular Weight: 234.018
• Mol File: 1632070-90-6.mol

Chemical Properties

• CAS DataBase Reference: C₇H₅BF₅^(1-)*K⁽¹⁺⁾(CAS DataBase Reference)
• NIST Chemistry Reference: C₇H₅BF₅^(1-)*K⁽¹⁺⁾(1632070-90-6)
• EPA Substance Registry System: C₇H₅BF₅^(1-)*K⁽¹⁺⁾(1632070-90-6)

Safety Data

• Hazardous Substances Data: 1632070-90-6(Hazardous Substances Data)

Upstream product

• 23915-07-3 1-(bromomethyl)-2,4-difluorobenzene 
• 73183-34-3 bis(pinacol)diborane 

Downstream Products

• 1632070-94-0 C₁₄H₉F₂N 

Relevant articles and documents

Dual Nickel- and Photoredox-Catalyzed Enantioselective Desymmetrization of Cyclic meso-Anhydrides

The enantioselective desymmetrization of cyclic meso-anhydrides with benzyl trifluoroborates under nickel-photoredox catalysis is described. The reaction tolerates a variety of sterically and electronically different trifluoroborates, as well as structurally unique cyclic anhydrides. The trans isomer of the keto-acid products is also observed at varying levels dependent on the trifluoroborate identity and relative catalyst loading. A mechanism involving decarbonylation and Ni?C bond homolysis of a NiII adduct is proposed. This feature allows access to a trans keto-acid as the major product in high enantioselectivity from a cis meso anhydride.