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163228-38-4

6-O-(tert-butyldimethylsilyl)-D-galactal cyclic carbonate is a chemical compound derived from D-galactal, a monosaccharide sugar. 6-O-(TERT-BUTYLDIMETHYLSILYL)-D-GALACTAL CYCLIC CARBONATE is characterized by the presence of a cyclic carbonate group and a tert-butyldimethylsilyl (TBDMS) protecting group at the 6-O position. The TBDMS group is commonly used in organic synthesis to protect hydroxyl groups from unwanted reactions, making it a valuable intermediate in the synthesis of various complex organic molecules, particularly in the field of carbohydrate chemistry. The cyclic carbonate structure provides additional stability and reactivity to the molecule, which can be further functionalized or deprotected as needed for specific applications.

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  • 163228-38-4 Structure

  • Basic information

    1. Product Name: 6-O-(TERT-BUTYLDIMETHYLSILYL)-D-GALACTAL CYCLIC CARBONATE
    2. Synonyms: 6-O-(TERT-BUTYLDIMETHYLSILYL)-D-GALACTAL CYCLIC CARBONATE;6-O-(tert-butyldimethylsilyl)-D-galactal cyclic C;2,6-Anhydro-5-deoxy-1-O-[(1,1-dimethylethyl)dimethylsilyl]-D-arabino-hex-5-enitol cyclic carbonate;6-O-tert-Butyldimethylsilyl-3,4-O-carbonyl-D-galactal
    3. CAS NO:163228-38-4
    4. Molecular Formula: C13H22O5Si
    5. Molecular Weight: 320.41
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 163228-38-4.mol

  • Chemical Properties

    1. Melting Point: 45-49 °C(lit.)
    2. Boiling Point: N/A
    3. Flash Point: >230 °F
    4. Appearance: /
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: 6-O-(TERT-BUTYLDIMETHYLSILYL)-D-GALACTAL CYCLIC CARBONATE(CAS DataBase Reference)
    10. NIST Chemistry Reference: 6-O-(TERT-BUTYLDIMETHYLSILYL)-D-GALACTAL CYCLIC CARBONATE(163228-38-4)
    11. EPA Substance Registry System: 6-O-(TERT-BUTYLDIMETHYLSILYL)-D-GALACTAL CYCLIC CARBONATE(163228-38-4)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany: 3
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 163228-38-4(Hazardous Substances Data)

163228-38-4 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 163228-38-4 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,6,3,2,2 and 8 respectively; the second part has 2 digits, 3 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 163228-38:
(8*1)+(7*6)+(6*3)+(5*2)+(4*2)+(3*8)+(2*3)+(1*8)=124
124 % 10 = 4
So 163228-38-4 is a valid CAS Registry Number.

163228-38-4 Well-known Company Product Price

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  • Aldrich

  • (MAR000016)  6-O-(tert-Butyldimethylsilyl)-D-galactalcycliccarbonate  AldrichCPR

  • 163228-38-4

  • MAR000016-500MG

  • 0.00CNY

  • Detail

163228-38-4SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 18, 2017

Revision Date: Aug 18, 2017

1.Identification

1.1 GHS Product identifier

Product name (4S,5S,6S)-6-[(1R)-2-[tert-butyl(dimethyl)silyl]oxy-1-hydroxyethyl]-5-hydroxy-2-oxo-1,3-dioxane-4-carbaldehyde

1.2 Other means of identification

Product number -
Other names 1,2-dideoxy-6-O-(tert-butyldimethylsilyl)-D-liso-hex-1-enopyranoside

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:163228-38-4 SDS

163228-38-4Relevant articles and documents

Selective Synthesis of Some Aminosugars via Catalytic Aminohydroxylation of Protected 2,3-Unsaturated d -Gluco- And d -Galacto-2-hexenopyranosides

Fukuhara, Ippei,Matsubara, Ryosuke,Hayashi, Masahiko

supporting information, p. 9179 - 9189 (2020/08/14)

The aminohydroxylation of methyl 4,6-di-O-(tert-butyldimethylsilyl)-2,3-unsaturated α-d-glucopyranoside proceeds in the presence of chloramine-T, OsO4 (4 mol %), (DHQ)2PHAL (5 mol %), and triethylbenzylammonium chloride (TEBAC) in both a stereoselective a

General Strategy for Stereoselective Synthesis of β- N-Glycosyl Sulfonamides via Palladium-Catalyzed Glycosylation

Dai, Yuanwei,Zheng, Jianfeng,Zhang, Qiang

, p. 3923 - 3927 (2018/07/21)

A highly efficient and mild glycosylation reaction between 3,4-O-carbonate glycal and N-tosyl functionalized aliphatic and aromatic amines via palladium-catalyzed decarboxylative allylation is disclosed. A wide range of highly functionalized 2,3-unsaturat

Application of glycals to the synthesis of oligosaccharides: Convergent total syntheses of the Lewis X trisaccharide sialyl Lewis X antigenic determinant and higher congeners

Danishefsky, Samuel J.,Gervay, Jacquelyn,Peterson, John M.,McDonald, Frank E.,Koseki, Koshi,Griffith, David A.,Oriyama, Takeshi,Marsden, Stephen P.

, p. 1940 - 1953 (2007/10/02)

Exploiting the differences in reactivity of the hydroxyl groups of glucal allows for rapid access to the sLex tetrasaccharide glycal. This compound is readily converted to the title compounds by azaglycosylation followed by deprotection. The us

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