163332-89-6Relevant articles and documents
Synthesis of 4-bromocubane-1-carbaldehyde
Shastin,Zakharov,Bugaeva,Eremenko,Romanova,Lagodzinskaya,Aleksandrov,Eremenko
, p. 1304 - 1306 (2006)
Oxidation of 4-bromo-1-hydroxymethylcubane and 1,4-bis(hydroxymethyl)cubane with the 2,2,6,6-tetramethylpiperidine-N-oxyl-trichloroisocyanuric acid-sodium bicarbonate system afforded the corresponding aldehydes. 4- Bromocubanecarbaldehyde was also obtained in high yield by reduction of 4-bromocubanecarboxylic acid and its methyl ester with bis(N-methylpiperazinyl) aluminum hydride. Springer Science+Business Media, Inc. 2006.
Cyclooctatetraenes through Valence Isomerization of Cubanes: Scope and Limitations
Houston, Sevan D.,Xing, Hui,Bernhardt, Paul V.,Vanden Berg, Timothy J.,Tsanaktsidis, John,Savage, G. Paul,Williams, Craig M.
supporting information, p. 2735 - 2739 (2019/02/07)
The scope and limitations of Eaton's rhodium(I)-catalyzed valence isomerization of cubane to cyclooctatetraene (COT) were investigated in the context of functional group tolerability, multiple substitution modes and the ability of cubane-alcohols to undergo one-pot tandem Ley–Griffith Wittig reactions in the absence of a transition metal catalyst.
Alkynylcubanes as precursors of rigid-rod molecules and alkynylcyclooctatetraenes
Eaton, Philip E.,Galoppini, Elena,Gilardi, Richard
, p. 7588 - 7596 (2007/10/02)
We have developed new methodology for the synthesis of alkynylcubanes and have used these compounds to make rigid-rod molecules constructed of cubane and acetylene subunits. Terminal and substituted alkynylcubanes 7a, 7b, 8a, 8b, 12a, and 12b were synthes
