163353-67-1Relevant articles and documents
Reaction of chlorosulfonyl isocyanate with fluorosubstituted alkenes: Evidence of a concerted pathway
Shellhamer, Dale F.,Davenport, Kevyn J.,Hassler, Danielle M.,Hickle, Kelli R.,Thorpe, Jacob J.,Vandenbroek, David J.,Heasley, Victor L.,Boatz, Jerry A.,Reingold, Arnold L.,Moore, Curtis E.
experimental part, p. 7913 - 7916 (2011/02/25)
Concerted reactions are indicated for the electrophilic addition of chlorosulfonyl isocyanate with monofluoroalkenes. A vinyl fluorine atom on an alkene raises the energy of a stepwise transition state more than the energy of the competing concerted pathw
Chlorination of oximes in hydrogen fluoride: formation of gem-dihalogenoalkanes
Tordeux, Marc,Boumizane, Khalid,Wakselman, Claude
, p. 207 - 214 (2007/10/02)
The action of chlorine on oximes in hydrogen fluoride as a medium gives gem-dihalogenoalkanes.The reaction proceeds through the intermediate formation of gem-chloronitrosoalkanes.The relative proportions between gem-dichloro, -difluoro and -fluorochloro compounds are dependent on the presence of a cosolvent.The use of other oxidants, such as nitric oxide, dinitrogen tetroxide or nitrosyl chloride, gives similar compounds: - Keywords: Chlorination, Oximes; Hydrogen fluoride; Dihalogenoalkanes; NMR spectroscopy, Mass spectrometry