16337-54-5

Basic information

• Product Name: Platinum,dichlorobis(triphenylphosphite-p-)-
• Synonyms: dichlorobis(triphenylphosphite-p-)-Platinum;Platinum,dichlorobis(triphenylphosphite-p-)-
• CAS NO: 16337-54-5
• Molecular Formula: C₃₆H₃₀Cl₂O₆P₂Pt
• Molecular Weight: 0
• Mol File: 16337-54-5.mol

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Platinum,dichlorobis(triphenylphosphite-p-)-(CAS DataBase Reference)
• NIST Chemistry Reference: Platinum,dichlorobis(triphenylphosphite-p-)-(16337-54-5)
• EPA Substance Registry System: Platinum,dichlorobis(triphenylphosphite-p-)-(16337-54-5)

Safety Data

• Hazardous Substances Data: 16337-54-5(Hazardous Substances Data)

Upstream product

• 101-02-0 triphenyl phosphite 
• 10025-65-7 platinum(II) chloride 
• 17457-51-1 dichlorobis(dimethylsulfide)platinum(II) 

Downstream Products

• 144613-94-5 Pt(C₂H₄){P(OC₆H₅)3}2 
• 198984-02-0 [Pt(triphenyl phosphite)3] 
• 1443116-62-8 cis-[PtH(Se(9-triptycyl)){P(OPh)₃}₂] 
• 1579984-49-8 (SP-4-2)-[Pt{κC,κP-(Z)-CH=C(Ph)OP(OPh)2}(Se(9-triptycyl))-{P(OPh)₃}] 
• 1443116-63-9 (SP-4-2)-[Pt{κC¹,κSe⁹-(9-triptycyl)Se(2-)}{P(OPh)₃}₂] 

Relevant articles and documents

Structure determination and DFT studies of some new phosphite-based cycloplatinated(II) complexes containing biphosphine ligands

The starting complex [PtCl{(κ2-P,C)P(OC6H4) (OPh)2}SMe2], 3, was prepared by a new method using the reaction of [PtCl2(P(OPh)3)2] with 1 equiv of PtCl2 in x

Characterization and phenylacetylene-assisted cyclometalation of an isolable hydrido-selenolato PtII complex having phosphite ligands, cis-[PtH(SeTrip){P(OPh)3}2]#

A hydridoselenolato PtII complex having P(OPh)3 ligands, cis-[PtH(SeTrip){P(OPh)3}2] (Trip: 9-triptycyl), was synthesized by the reaction of TripSeH with [Pt{P(OPh)3} 2]. The structure was characterized by NMR spectroscopy and X-ray crystallography in comparison with the corresponding PPh3 complex, cis-[PtH(SeTrip)(PPh3)2], indicating the stronger coordination of P(OPh)3 to the Pt center than that of PPh 3. On heating at 130 °C in xylene for 17 h, cis-[PtH(SeTrip)- {P(OPh)3}2] was converted to the corresponding 1,2-selenaplatinacycle (SP-42)-[Pt(kC1,kSe9-TripSe(2-)) {P(OPh)3}2] through an intramolecular cyclization (cyclometalation). The reaction with dimethyl acetylenedicarboxylate (DMAD) gave a mixture of hydroselenation products (E)- and (Z)-(MeO2C)CH= C(SeTrip)CO2Me non-stereoselectively together with 1H-2-benzoselenin, dimethyl 7H-7,11b[1',2']-benzenoanthra[9,1-bc]selenin-2,3-dicarboxylate. In the reaction with phenylacetylene in toluene at 110 °C, phenylacetylene served as a hydrogen acceptor to form the 1,2-selenaplatinacycle and styrene. Based on the results of controlled experiments using cis-[PtD(SeTrip){P(OPh) 3}2] and phenylacetylene-d, the mechanism of the cyclometalation was proposed as the 1,2- (major) and 2,1- (minor) insertions of phenylacetylene into the Pt-H bond followed by cyclometalation between the Pt center and the triptycyl group. The reaction with phenylacetylene in the presence of excess P(OPh)3 furnished a 1,2,3-oxaphosphaplatinacycle, (SP-4-2)-[Pt{kC,kP-(Z)-CH=C(Ph)-OP(OPh)2}(SeTrip){P(OPh) 3}], as a minor product, together with the 1,2-selenaplatinacycle in a decreased yield.